• Stevie Wonder, Pharrell Williams head line-up at Montreux Jazz

Stevie Wonder, Pharrell Williams head line-up at Montreux Jazz (Photo : Steve Marcus/Reuters)

James Corden could not hold his tears as he listened to Stevie Wonder's unbelievable voice in the Carpool Karaoke segment of his show.  

Rollingstone reported that the two had great chemistry and it was immediately evident at the beginning of the clip as Corden is nervous that Wonder is driving, then the latter discovers that he does not have his license.

Like Us on Facebook

The host breathed a sigh of relief and offered to take the wheel instead, while within a few seconds, the carpool duo started to belt out "Superstition."

The legendary singer poked fun at Corden's British accent and even called a family member to check if he is indeed riding with him because for Wonder "all English guys look alike."

The iconic singer also advised the 37-year-old British host to never try playing the harmonica.

The emotional moment happened when Corden asked Wonder to call his wife, who's a huge fan of the singer. According to Wired, not only did he call but he also serenaded her with his timeless classic "I Just Called to Say I Love You."

The singer also changed it up to say "I Just Called to Say James Loves You," melting the heart of the host.

In the 10-minute video is worth every second as the two sang chart-topping hits like "Isn't She Lovely," "For Once in My Life," and "Signed, Sealed, Delivered."

The carpool buddies even thought of forming their own group called the "Wondercats." Corden suggested that they will create a futuristic vibe for the group and even offered to dance on top of the piano clad in neon outfit.

Wonder returns on stage in "Songs in the Key of Life" performance tour which will kick off in Montreal on Sept. 30, 2015.

Watch the memorable video below!